I am referencing B. Schutz, A First Course in General Relativity. 2009, p. 256-258.
Note first that the line element on a 2-sphere with radius of curvature $r$ is $dl^2=r^2(d\theta^2+\sin^2\theta d\phi^2)$. Since we want a metric that is spherically symmetric about a point in space, say $r'=0$, we must not be able to tell the difference (in terms of intrinsic geometry) between points located at the same distance $r'$ away from the centre of symmetry and at the same time $t$. Therefore every point in space-time is located on a spatial 2-sphere whose radius of curvature may depend on coordinates $r'$ and $t$, i.e. $r=r(r',t)$. The line element on such a 2-sphere is then $dl^2=r^2(d\theta^2+\sin^2\theta d\phi^2)$, where we have chosen to label each sphere by its radius of curvature $r$ instead of the actual radial distance $r'$ of its points away from the centre of symmetry.
Now consider two spheres corresponding to the same time $t$ but different distances $r'$ and $r'+dr'$. A priori, the coordinates on the two spheres might be defined with respect to different poles where $\theta=0$ and different half-planes where $\phi=0$. However, because the spheres are centred about the same point $r'=0$, we can always choose these references to be the same such that the curves $\theta=const.$, $\phi=const.$ (implicity, we also have $t=const.$) are orthogonal to all spheres at different distances $r'$. By definition, a tangent to these curves is the coordinate basis vector $\textbf{e}_r$. Therefore we have $g_{\theta r}=\textbf{e}_{\theta}\cdot\textbf{e}_r=0$ and $g_{\phi r}=\textbf{e}_{\phi}\cdot\textbf{e}_r=0$. We have thus reduced the most general metric in spherical coordinates, with all the possible cross terms, to the slightly simpler form: $$ds^2=g_{00}dt^2+2g_{0r}dtdr+2g_{0\theta}dtd\theta+2g_{0\phi}dtd\phi+g_{rr}dr^2+r^2d\Omega^2,$$ where I have defined $d\Omega^2\equiv d\theta^2+\sin^2\theta d\phi^2$.
Similarly, we argue that the curves $r=const.$, $\theta=const.$, $\phi=const.$, with tangent vector $\textbf{e}_t$ must be orthogonal to the two-spheres. Otherwise, $\textbf{e}_t$ would have components in the directions of $\textbf{e}_\theta$ and $\textbf{e}_\phi$. There would then be a preferred spatial direction on the 2-sphere, namely that direction parallel to the projection of $\textbf{e}_t$ on the sphere. But this is forbidden by spherical symmetry, therefore $g_{0\theta}=\textbf{e}_t\cdot\textbf{e}_\theta=0$ and $g_{0\phi}=\textbf{e}_t\cdot\textbf{e}_\phi=0$. We have now reduced the metric to: $$ds^2=g_{00}dt^2+2g_{0r}dtdr+g_{rr}dr^2+r^2d\Omega^2.$$ Lastly, a static spacetime is one where the metric is unchanged by a transformation $t \rightarrow -t$. This implies that $g_{0r}=-g_{0r}=0$. Therefore we get a line element that only contains $dt^2$, $dr^2$ and $r^2\Omega^2$, as required by the question.