To answer this question first you must consider how is linear and angular momentum defined. (Here point C designates the center of mass).
- Linear momentum is the product of the scalar mass with the linear velocity of a rigid body at the center of mass $$\mathbf{p} = m \mathbf{v}_C$$
- Angualar momentum at the center of mass is defined as the product of the mass moment of inertia tensor at the center of mass and the rotational velocity vector $$\mathbf{L}_C = \mathrm{I}_C \boldsymbol{\omega}$$
The reason for this distinction is the linear momentum describes the motion of the center of mass and angular momentum the motion about the center of mass. This separation comes naturally out of the equations when summing up the movement of all the particles on a rigid body.
Once you have accepted the above definitions you find the following:
- Net force equals the time derivative of linear momentum
$$\sum \mathbf{F} = \frac{{\rm d}}{{\rm d}t} \mathbf{p} = m \frac{{\rm d}}{{\rm d}t} \mathbf{v}_C = m \, \mathbf{a}_C $$
- Net torque about the center of mass is the time derivative of angular momentum about the center of mass
$$ \sum \boldsymbol{\tau} = \frac{{\rm d}}{{\rm d}t} \mathbf{L}_C = \mathrm{I}_C \left( \frac{{\rm d}}{{\rm d}t} \boldsymbol{\omega} \right) +\left( \frac{{\rm d}}{{\rm d}t} \mathrm{I}_C \right) \boldsymbol{\omega} = \mathrm{I}_C \boldsymbol{\alpha} + \boldsymbol{\omega} \times \mathrm{I}_C \boldsymbol{\omega}$$
So the key here is that a net zero force will cause the center of mass no acceleration (constant velocity = Newton's 1st law) and thus a pure torque will rotate a body about the center of mass. The differentiation of angular momentum retains the disclaimer "about the center of mass" that we establised in the first part of this answer.
The following two statements are true and dual to each other (if one is true, so must the other). They are both a result of the definition of the center of mass.
- A net pure torque accelerates a rigid body about the center of mass
- A force through the center of mass accelerates a body with pure translation.
Reference: Derivation of Newton-Euler equations of motion.