As you already noted, a positive Lyapunov exponent (if properly ensured with surrogates, etc.) can tell you whether a system is chaotic. However, the differentiation to make is not only between chaos and regular dynamics¹, but between chaos and a stochastic dynamics². Somewhat simplified you want to distinguish between a finite positive and an infinite Lyapunov exponent.
Now, what is the practical value of this?
If we know the system is chaotic and not stochastic, we may manipulate it to some extent, e.g., using chaos control.
A chaotic system can be predicted to some extent, which in turn may allow for targeted interventions.
The Lyapunov exponent tells us how far we can predict the system with a given knowledge about it.
For example, the Lyapunov exponent of the weather gives us a natural limit of weather forecasts.
It guides us on how to approach modelling a system, more precisely on whether to use a stochastic or deterministic model.
This is admittedly not very practical, but the models in turn may help us understand a system and have a lot of practical implications.
If we know that we are experimenting with a chaotic system, we can have some expectations on how replicates of the same setup will behave.
¹ If you really have a regular dynamics, it’s usually pretty obvious.
² More precisely:
A dynamics dominated by inaccessible stochastic components.
Most real systems have stochastic and deterministic components, where stochastic merely means that it is beyond the scope of our models and measurements, e.g., molecular billiard when investigating a chemical reaction in a tube.