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In the Debeye approximation the density of states goes with phonon-energy^2, while the density of states for free electrons goes with sqrt(energy of the electrons), why is that?

(I use Introduction to Solid State Physics, Charles Kittel as learning book.)

Qmechanic
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Mari3
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1 Answers1

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The density-of-states is given by $$D(E) \propto \int dk_x dk_y dk_z \delta\left[E-\epsilon(\mathbf{k})\right],$$ where I omitted the prefactor for simplicity. The result of this integration depends on the form of the dispersion law $\epsilon(\mathbf{k})$. Assuming that the dispersion is isotropic (which is really rarely the case in real materials) we have for electrons $$\epsilon(\mathbf{k}) = \frac{\hbar^2k^2}{2m},$$ whereas for phonons $$\epsilon(\mathbf{k}) = vk.$$ The integration in the density of states is reduced to the integration over the magnitude of the momentum (after transition to the spherical coordinates): $$D(E)\propto 4\pi \int_0^{+\infty}dk k^2\delta\left[E-\epsilon(k)\right]= \frac{4\pi (k^*)^2}{\left|\frac{d\epsilon(k)}{dk}|_{k=k^*}\right|},$$ where $k*$ is determined from the equation $E=\epsilon(k^*)$, which for electrons gives $$k^*=\frac{1}{\hbar}\sqrt{2mE}, \frac{d\epsilon(k)}{dk}|_{k=k^*} = \frac{\hbar^2k^*}{m},$$ whereas for phonons $$k^* = v, \frac{d\epsilon(k)}{dk}|_{k=k^*} = v.$$ Thus for electrons the density-of-states behaves as $D(E)\propto k* \propto \sqrt{E}$, whereas for phonons it is $D(E)\propto (k^*)^2\propto E^2$.

Finally, it is worth noting that the results are different, if this calculation is done in two or one dimensions, which is quite relevant for nanostructure physics.

Roger V.
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