In special relativity we know that there is no notion of absolute simultaneity that holds for all inertial frames. Instead, we would send light signals to and from distant clocks (to synchronize them) and events (to measure whether or not they were simultaneous). In both of the cases, it seems like there is no "direct" way to establish or measure simultaneity.
What makes this worse is that we have to presuppose that the speed of light is the same in all directions (and it is known that there can't be any measurement of one-way speed of light). This seems like a heavy assumption.
All of this leads me to the following questions (assume theoretical units where $c=1$):
Given coordinates $(t, x)$ of an inertial frame, we know the planes of simultaneity are solutions to $t=\text{const}$. This makes sense, but then why can't I consider the coordinates $(\widetilde{t}, \widetilde{x}) = (t+x/2, x)$ and then declare simultaneity to be the solution to $\widetilde{t}=\text{const}$? What would be wrong with the new coordinates? Why can't (or shouldn't) I use them?
Even if the $(\widetilde{t}, \widetilde{x})$ are not well-motivated, I can consider something like Rindler coordinates. Is there any sense in talking about simultaneity in the context of Rindler coordinates? Is it just not defined there?
In general relativity we are forced to use curvilinear coordinates. People almost always brush under the rug the idea of simultaneity. Is it just something that only approximately applies to local reference frames (where $ds^{2}\approx dx^{2} - dt^{2}$)? What if we consider the Schwarzschild solution with two people at different radii away from the black hole. Is there any sense in talking about synchronizing their clocks if they are far away from each other? Maybe we can take $t=\text{const}$ in the Schwarzschild coordinates, but here we see that $t=\text{const}$ is an artefact of the coordinates, and we can construct different coordinates whose notion of $t=\text{const}$ is different.
Is there a rigorous definition of simultaneity that would make sense of all three previous questions?
I realize this is sort of a semantics question above all else. However, semantics can be important too lest one starts having incorrect understanding of the fundamentals.