In Classical Mechanics angular velocity, angular acceleration, torque and angular momentum can be defined as vectors with clear advantages such as the possibility to use vector product to simplify expressions.
As someone who appreciates the symmetry between translational and rotational dynamics writing angular velocity as the derivative of the angle seems somewhat elegant to me, however this is not accurate when using vectors. This could be solved by defining an "angle vector". Why has this not common? Wouldn't it work?
I can imagine $\vec{\theta}$ perpendicular to the plane the angle lies on and with magnitude equal to its size in radians.