This question is similar to (but more specific than) this one: When are two proofs of the same theorem really different proofs
I do not know very much about homotopy type theory, but I am trying to understand how essentially different proofs of the same identity claim may naturally appear in Martin-Löf's intentional intuitionistic type theory.
So, I am looking for an (explicit, as simple as possible) example of a type $A$ with terms $a,b: A$ and identity proofs $p,q: \mathrm{Id}_A(a,b)$ such that the type $\mathrm{Id}_{\mathrm{Id}_A(a,b)}(p,q)$ is empty. (I am not sure I have by this correctly formulated my original intention. Homotopically, I want two non-equivalent paths, but I want it in type theory form.)