What I'm about to say apply only to Lie groups with finite-dimensional Lie algebras. In this case, there can be a natural choice of metric for the Lie group under some assumptions. The relevant constructions are defined in the Lie algebra of the group.
In the Lie algebra $\mathfrak{g}$, we can define, for every element $X \in \mathfrak{g}$, the adjoint action on the algebra itself given by its Lie bracket $ad_X(.)=[X,.]$. Now, we can define a symmetric bilinear form on $\mathfrak{g}$, the Killing form, by $B(X,Y)=Tr(ad_X ad_Y)$, since $ad_X$ can be expressed in term of a matrix acting on the vectors of the Lie algebra. We now have that this form will also be non-degenerate iff $\mathfrak{g}$ is semi-simple (Cartan criterion). This form is now only defined on the tangent space over the identity of the group. We can define a metric by using the fact that any tangent space can be mapped, for such a Lie group, to the tangent space over the identity. This metric may not be positive-definite, but in certain case, as if the Lie group is compact, the Killing form is negative-definite and thus, we can form a positive-definite metric by using $-B(X,Y)$.
Now, the Killing form will be invariant under $ad$. Taking the Lie derivative with respect to $X \in \mathfrak{g}$ of the above-defined metric, we will obtain $B(ad_X(Y),Z) - B(Y,ad_X (Z)) = 0$. When extending this $X$ to a right invariant vector field on the Lie group, this property is maintained, meaning that this vector field is Killing, or composed of Killing vectors. This shows that there is a way to relate some Killing vectors to the underlying group.
Concerning your question about a quantum field theory over Lie group, I am not so sure. If you choose the above metric, than you also have symmetries generated by the Killing fields obtained via the Lie algebra structure. This then implies that your QFT fields need to be representations for the group of these symmetries.