So lets think that solid is energy, then why we are not using it for our purposes?
We are.
In civilian nuclear energy production, atoms of (usually) Uranium-235, are being split ('fissioned' in the nuclear jargon) into fission products.
There is a small mass difference between the original fissile atoms (U-235) and the fission products:
$$m_{fissile}-m_{fissioned}>0.$$
And that difference has been converted to energy according to:
$$E=(m_{fissile}-m_{fissioned})c^2.$$
Consider $c^2$ a proportionality constant and because $c$ is large only small amounts of mass need to be converted to get appreciable amounts of energy.
Mass is converted to energy (and vice versa) all the time, even in everyday processes: when you wind up a Grandfather's clock (charge it with energy), it becomes slightly heavier (albeit only imperceptibly little).
To convert mass to energy at an appreciable (i.e. commercially viable) rate we need to tap into the strongest forces in nature: the nuclear forces. Hence the generation of nuclear energy.