Let be $G$ a Lie Group and $\textbf{N}$ its complex representation.
It is known that any state $|\ ab\ \rangle\in \textbf{N}\otimes\textbf{N} = \oplus_I\textbf{r}_I$ may be decomposed through the Clebsch-Gordan decomposition, to wit $$ |ab\rangle = \sum_{I,i} C^{ab}_{Ii}|I,i\rangle \tag1 $$ where $I$ is a collective index for each irrep, and I am assuming there are no degenerate invariant subspaces in the decomposition.
I can also use a tensor notation instead of the bra-ket one. So I denote the single state $| a \rangle$ transforming under $\textbf{N}$ as $\pi^a$.
Can I write $$ \pi^a\pi^b = \sum_{I,i}\sum_{\phi} C^{ab}_{Ii}\phi^{Ii} \tag2 $$ where $\phi^{Ii}$ is a tensor which transforms under $\textbf{r}_I$? In this case, how can I identify the Clebsch-Gordan coefficients?
For example for SU(3), $\textbf{3}\otimes\textbf{3}=\textbf{6}+\bar{\textbf{3}}$ and the tensor decomposition reads $$ \pi^a\pi^b = \frac{1}{2}\left(\pi^a\pi^b + \pi^b\pi^a\right) + \frac{1}{2}\left( \pi^a\pi^b-\pi^b\pi^a \right) $$ How can I write this in the form indicated in $(2)$?