So, my question deals with the excited electron shown above. (1st diagram) This electron can return to its ground state by either of two ways. One of the ways involves the emission of 2 photons. (2nd diagram) And the other way involves the emission of only 1 photon. (3rd diagram)
The total energy of the 2 photons shown in the 2nd diagram is the same as the total energy of the 1 photon shown in the 3rd diagram. So, my question is: would the first 2 photons together produce a colour that is the same as the colour of the 3rd photon (assuming the 2 photons from the 2nd diagram travel in the same direction) ? If not, then why not, and how different would the mixture of colours from the first 2 photons be from the colour of the last photon?