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In general, to obtain the time dependence of an arbitrary wave packet $\left| \phi(x)\right>$ in the Schödinger picture, we expand the wave packet in the energy eigenfunction basis $\left| \psi_n(x)\right>$

$$\left| \phi(x)\right> = \sum_\limits{n} \left< \psi_n(x) | \phi(x)\right> \left| \psi_n(x)\right>$$

Then we solve the time dependent equation:

$$\left| \phi(x, t)\right> = \sum_\limits{n} \left< \psi_n(x) | \phi(x)\right> \left| \psi_n(x)\right> e^{-iE_nt\hbar}$$

  1. Can the time dependent equation be applied to the wave packet itself $\phi(x)$ without using the energy eigenfunctions?

  2. I think it might be possible to do so by using the time dependent Schödinger equation considering the wave packet as a function of $x$ and $t$ (equation below). Am I right?

$$\left[-\frac{\hbar}{2m}\nabla^2 + V(x)\right]\phi(x, t) = i\hbar\frac{\partial \phi}{\partial t}$$

Qmechanic
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lytex
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1 Answers1

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Here is a possible suggestion how such an approach might work. The mechanism follows from rather general considerations and does not require quantum mechanics. So I'll use a more general mathematical notation.

Imagine I want to know the time evolution $f(x,t)$ when I only have knowledge of the initial condition $f(x,0)$. The assumption is that there is some dynamics that uniquely fixes $f(x,t)$, given $f(x,0)$. One can express the dynamics by some linear operator (linear equation of motion).

One way, as you pointed out, is to expand the solution in terms of the eigen-functions (let's briefly review it) $$ f(x,t) = \int F(\omega) \phi(x,\omega,t)\ d\omega . $$ Here $\phi(x,\omega,t)$ are the eigen-functions and they are indexed by $\omega$ (associated with the energy). These eigen-functions are also orthogonal in the sense that $$ \int \phi(x,\omega,t) \phi^*(x,\omega',t)\ dx = \delta(\omega-\omega'). $$

This now allows us to obtain the spectrum for $f(x,0)$ at $t=0$ using $$ F(\omega) = \int f(x,0) \phi^*(x,\omega,0)\ dx . $$ Then we can substitute $F(\omega)$ into the original expansion to get a general expression for $f(x,t)$ that is valid for all time.

Now for the alternative approach. Imagine we do the substitution, just mentioned and then change the order of integration $$ f(x,t) = \int f(x',0) \int \phi^*(x',\omega,0) \phi(x,\omega,t)\ d\omega \ dx'. $$ The inner integral now represents a Green function or propagator for the process $$ K(x,x',t) = \int \phi^*(x',\omega,0) \phi(x,\omega,t)\ d\omega. $$ If the dynamics is translation invariant in $x$, we'll get $$ K(x-x',t) = \int \phi^*(x',\omega,0) \phi(x,\omega,t)\ d\omega. $$ If we substitute this back we obtain a convolution integral $$ f(x,t) = \int f(x',0) K(x-x',t)\ dx'. $$

So this provides an alternative approach. However, one needs to know the Green function, or alternatively derive it from knowledge of the eigen-functions.

flippiefanus
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