Suppose I have a mass sitting on a surface with friction. Now I start pushing on the mass in one direction (call this direction the x direction). To get this mass accelerating, I have to push the mass with a force greater than $\mu_{s}mg$. Assuming the force is large enough such that the mass moves until there is a significant x component of velocity.
Now here's where my question arises. While this mass is moving in the x direction suppose I decide to push it along a direction orthogonal to it's motion (call this direction y). Is the minimum force required to get the mass to move in the y direction going to be $\mu_{s}mg$ or is it $\mu_{k}mg$ since the object is already moving?
How would I think of this problem in terms of a microscopic model of friction?