If quarks come in three colours $r$, $g$ and $b$ than (neglecting all other quantum numbers and spacial freedom for now) a state of a quark would be a vector in $\mathbb{C}^3$.
If we are now looking for a global symmetry redefining the colours than I would be left with the unitary group $U(3)$. However the correct gauge group is $SU(3)$.