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This may come a bit elemental, what I was working on a direct way to find the eigenfunctions and eigenvalues of the isotropic two-dimensional quantum harmonic oscillator but using polar coordinates:

$$ H=-\frac{\hbar}{2M}\left(\frac{\partial^2}{\partial x^2}+\frac{\partial^2}{\partial y^2}\right)+\frac{M\omega^2}{2}\left(x^2+y^2\right). $$

I can easily solve the 2-dimensional case in cartesian coordinates as we can separate the hamiltonian in independent oscillators for each coordinate. For the polar case in two dimensions, we can rewrite,

$$H=-\frac{\hbar}{2M}\left(\frac{\partial^2}{\partial r^2}+\frac{1}{r}\frac{\partial}{\partial r}+\frac{1}{r^2}\frac{\partial^2}{\partial \phi^2}\right)+\frac{\omega^2}{2}r^2.$$

With $r^2=x^2+y^2$ and $\phi=\arctan(y/x)$.

Using separation of variables $\psi(r,\phi)=R(r)\Phi(\phi)$ and plugging into the Schrödinger equation, we can easily solve for the angular part $\Phi=e^{im\phi}$, where $m\in \mathbb{Z}$.

Plugging back into the Schrodinger equation, for the radial part, we get:

$$r^2R''+rR'+(r^2E-m^2-M\omega^2r^4)R=0.$$

While I have an idea for the solution by making an analogy with the 3D case (where we get Laguerre polynomials), I'm not sure how to correctly proceed from here. I appreciate any input or even useful references* (all of the references I've found deal with the 3D case, which I have no problem solving).

*I read online this problem is treated in the book of "Wave Mechanics" from Pauli, but unfortunately it isn't available on neither of my campus libraries nor online (it's only available for purchase and I lack the funds to buy it).

Qmechanic
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Charlie
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  • Thanks for the typo, I indeed forgot the last $R$. On the other hand, I indeed looked at those articles but they have specific solutions, and I was looking to construct the general one in terms of special functions. – Charlie Nov 06 '18 at 18:14

2 Answers2

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Indeed, as suggested by phase-space quantization, most of these equations are reducible to generalized Laguerre's, the cousins of Hermite. As universally customary, I absorb $\hbar$, M and ω into r,E. Note your E is twice the energy.

Since $r\geq 0$ you don't lose negative values, and you may may redefine $r^2\equiv x$, so that $$ r\partial_r = 2x \partial_x \qquad \Longrightarrow r\partial_r (r\partial_r)= r^2\partial_r^2+ r\partial_r=4(x^2\partial_x^2+x\partial_x), $$ hence your radial equation reduces to $$ \left ( \partial_x^2+ \frac{1}{x}\partial_x +\frac{E-x}{4x} -\frac{m^2}{4x^2} \right ) R(m,E)=0 ~. $$

Now, further define $$ R(m,E)\equiv x^{|m|/2} e^{-x/2} ~ \rho(m,E), $$ to get $$ \partial_x R(m,E)= x^{|m|/2} e^{-x/2} \left (-1/2 +\frac{|m|}{2x} + \partial_x \right )~ \rho(m,E) \\ \partial_x^2 R(m,E)= x^{|m|/2} e^{-x/2} \left (-1/2 +\frac{|m|}{2x} + \partial_x \right )^2~ \rho(m,E), $$ whence the generalized Laguerre equation for non-negative m=|m|, $$ x \partial_x^2\rho(m,E) +\left({m+1} -x\right )\partial_x \rho(m,E)+\frac{1}{2}(E/2-m-1) \rho(m,E)=0~. $$ This equation has well-behaved solutions for non-negative integer $$k=(E/2-m-1)/2\geq 0 ~,$$ to wit, generalized Laguerre (Sonine) polynomials $L^{(m)}_k (x)=x^{-m}(\partial_x -1)^k x^{k+m}/k!$.

Plugging into the factorized solution and the above substitutions nets your eigen-wavefunctions. The ground state is $k=0=m$, ($E=2$ in your conventions), so a radially symmetric Gaussian, $e^{-r^2/2}$.

Again, in your idiosyncratic convention, the degeneracy is E/2.

So, degeneracy 2 for $E=4$ : $m=1$, $k=0$; you may check this is just $r e^{-r^2/2 +i\phi} $. You may choose the $\cos \phi$ and $\sin \phi$ solutions, if you wish, constituting a doublet of the underlying degeneracy group SU(2).

Cosmas Zachos
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  • I see, so indeed we should get Laguerre polynomials. I'll repeat the calculations according to what you put so I grasp the solution for this case and the general one. By the way, what do you mean by idiosincratic convention? If you refer to the case that m=1 I think someone badly edited my OP since I was actually working in the general case with arbitrary $m$ and $\omega$. I don't know why they removed the $m$ and $\omega$ (they didn't even leave it in natural units). – Charlie Nov 06 '18 at 18:13
  • the energy is E /2 as things stand.... – Cosmas Zachos Nov 06 '18 at 20:59
  • You gave an argument that k is an integer, but what about m? It seems that one would only get it to take (non-complex) integer values by assuming the angular functions to be continuous. – user510186 Jan 13 '22 at 17:46
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    Of course: it is in the statement of the OP. – Cosmas Zachos Jan 13 '22 at 18:03
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    Indeed. It seems that one can get the continuity argument from the assumption that H be symmetric. – user510186 Jan 13 '22 at 20:32
  • Sorry, but there is another question: I followed your math and obtained the same, except with your ansatz using $|m|$ I get a factor $|m|+1-x$ instead of $m+1-x$. The former is actually fine, but the weird thing is that then I do not see why E should be bounded below (which it should be). – user510186 Jan 13 '22 at 20:51
  • Sorry, I don't recall the minutiae of the generalized Laguerre equation. m=|m| else something would snag otherwise... – Cosmas Zachos Jan 13 '22 at 21:01
  • I checked it again, I made a mistake as well: We actually have $k=(E/2-|m|-1)/2$ above, so the energy is indeed bounded below by the correct value. All $m$s in the coefficients of the generalized Laguerre equation above should be $|m|$ instead. – user510186 Jan 13 '22 at 21:17
  • Fair enough... It's standard to take them non-negative, unless explicitly commented otherwise... – Cosmas Zachos Jan 13 '22 at 21:23
  • Sorry, but only taking positive $m$ does not work. One needs the negative $m$ in order to be able to span the entire Hilbert space of square-integrable functions for the angular part. – user510186 Jan 13 '22 at 21:28
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    Edited question. Now m=|m| summarizes both positive and negative m at the level of the solutions of the g-Laguerre equation, as the solutions are manifestly functions of |m| . – Cosmas Zachos Jan 14 '22 at 14:59
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I think you may have a factor of 2 error for the $E$ and the power of $M$, here is my derivation, I use $\theta$ instead of $\phi$.(we may double check) In polar coordinates, the Del operator $\nabla^2$ is defined as: $$ \begin{align} \nabla^2 &=\frac{1}{r} \frac{\partial}{\partial r}\left(r \frac{\partial f}{\partial r}\right)+\frac{1}{r^{2}} \frac{\partial^{2} f}{\partial \theta^{2}}\\ &=\frac{\partial^2 f}{\partial r^2}+\frac{1}{r} \frac{\partial f}{\partial r}+\frac{1}{r^{2}} \frac{\partial^{2} f}{\partial \theta^{2}} \end{align} $$ Then the Shrodinger Equation for this system can be written as: $$ \left(-\frac{\hbar^2\nabla^2}{2M}+\frac{M\omega^2r^2}{2}\right)\Psi(r,\theta)=E\Psi(r,\theta)\\ \left(-\frac{\partial^2}{2M\partial r^2}-\frac{1}{2Mr} \frac{\partial}{\partial r}-\frac{1}{2Mr^2} \frac{\partial^{2} }{\partial \theta^{2}}+\frac{M\omega^2r^2}{2}\right)\Psi(r,\theta)=E\Psi(r,\theta)\\ \left(-\frac{\partial^2}{\partial r^2}-\frac{1}{r} \frac{\partial}{\partial r}-\frac{1}{r^2} \frac{\partial^{2} }{\partial \theta^{2}}+M^2\omega^2r^2\right)\Psi(r,\theta)=2ME\Psi(r,\theta) $$ By assuming that the solution is separatable $\Psi(r,\theta)=R(r)\psi(\theta)$, we can solve the angular part fairly easily: $$ \psi(\theta)=e^{im\theta}\qquad m=0,1,2\dots $$ The the radia part can be rearraged when substitude the angular solution into the Scrodinger equation: $$ r^2R''+rR'+ \left(2r^2ME-m^2-M^2\omega^2r^4\right)R=0 $$ The equation can be simplfied by setting $M=\omega=1$ $$ r^2R''+rR'+ \left(2r^2E-m^2-r^4\right)R=0 $$