The field operator has a continuous spectrum (that is, a continuum of "eigenvalues"), so an "eigenstate" of the field operator would not be normalizable: the Hilbert space does not include any such state-vector. Therefore, its inner product with the vacuum state is undefined.
However, if the (free) field operator is written in terms of creation and annilation operators in the usual way, then we can define an eigenstate of the annihilation-operator part of the (smeared) field operator, and this is a coherent state. This is analogous to the usual single-mode coherent states
$$
|\alpha\rangle\equiv\exp(\alpha a^\dagger)|0\rangle
\tag{1}
$$
where $\alpha$ is a complex number.
In the free-scalar-field case, we have
$$
|\alpha\rangle \equiv
\exp\left(\int \frac{d^3p}{(2\pi)^3}\
\alpha(\mathbf{p})a^\dagger(\mathbf{p})\right)
|0\rangle
\tag{2}
$$
instead, where $\alpha(\mathbf{p})$ is a suitable complex-valued function. This is an eigenstate of the smeared annihilation operator
$$
a(\beta)\equiv\int \frac{d^3p}{(2\pi)^3}\
\beta^*(\mathbf{p})a(\mathbf{p}).
\tag{3}
$$
Use
$$
\big[a(\mathbf{p}),\,a^\dagger(\mathbf{q})\big]
=(2\pi)^3\delta(\mathbf{p}-\mathbf{q})
\hskip2cm
a(\mathbf{p})|0\rangle=0.
\tag{4}
$$
to get
$$
a(\beta)\,|\alpha\rangle = \left(\frac{d^3p}{(2\pi)^3}\
\beta^*(\mathbf{p})\alpha(\mathbf{p})\right)\,|\alpha\rangle.
\tag{5}
$$
The inner product $\langle\alpha|0\rangle$ can be calculated by adapting the techniques used in the single-mode case.
Since the creation and annihilation operators can conversely be expressed in terms of the field operator and its canonical conjugate, the preceding equations can also be re-expressed in those terms.
By the way, notice that the annihilation-operator part of $\phi(\mathbf{x})$ is a non-local operator. If we write $\phi^\pm(\mathbf{x})$ for the annihilation- and creation-parts, then the commutator of $\phi^-(\mathbf{x})$ with $\phi^+(\mathbf{y})$ is non-zero even when $\mathbf{x}\neq \mathbf{y}$. This is unavoidable, because the Reeh-Schlieder theorem implies that an operator that is strictly localized in any bounded region of spacetime cannot annihilate the vacuum state (section 2 in "Notes on Some Entanglement Properties of Quantum Field Theory", http://arxiv.org/abs/1803.04993).