The canonical quantization of a scalar field $\phi(x)$ can explicitly be realized in the space of functionals in fields $\phi(\vec x)$ (here $\vec x$ is spacial variable) by operators \begin{eqnarray} \phi(\vec x,0)\to \mbox{ multiplication by } \phi(\vec x,0),\\ \pi(\vec x,0)\to (-i)\frac{\delta}{\delta \phi(\vec x)}. \end{eqnarray} Thus, as usual, $[\phi(\vec x,t),\pi(\vec y,t)]=i\delta^{(3)}(\vec x-\vec y)$. (See e.g. $\S$ 9.1 in S. Weinberg's book "The QFT", particularly the discussion after formula (9.1.40).)
I am looking for an analogous realization of canonical quantization of a fermionic field. At the moment the case of a free fermionic field is enough for me. In addition I would be interested to know how the vacuum vector in this space looks like; more concretely I would like to know the explicit form of $\epsilon$-terms in (9.5.49) in Weinberg’s book.
The discussion of the fermionic case in Weinberg's book is not as detailed as in the scalar case.