-2

This was discussed before proving the node theorem.

Qmechanic
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shashank
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1 Answers1

1

The 1D TISE is a second-order homogeneous ODE. The complete solution span a 2-dimensional vector space parametrized by 2 constants. It is not hard to see that if a solution and its derivative vanish in the same point, it must be the zero-solution. The zero-solution is unacceptable as a wave-function.

Qmechanic
  • 201,751