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Why for a given temperature these forms of Wien's law implies a different maximal wavelength?

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Qmechanic
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Arrara
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    Do they? I haven't done the calculations to verify the exact numbers stated, but remember $\nu$ is the frequency, which is equal to $c/\lambda$. It looks like the equations in terms of the exact constants are correct. – Jack Ceroni Oct 02 '19 at 03:13
  • I carried out a computation fro $T = 6000 \ {\mathrm K}$. It leads to results $\nu = 352 \ {\mathrm THz}$ and $\lambda = 849 \ {\mathrm nm}$ for the equation $\nu_{max}$ and to results $\nu = 620 \ {\mathrm THz}$ and $\lambda = 482 \ {\mathrm nm}$ for the equation $\lambda_{max}$ . So are they two different functions? – Arrara Oct 02 '19 at 03:50
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    @JackCeroni They’re different. The $x$ in the two formulas is not the same number. See https://en.wikipedia.org/wiki/Wien's_displacement_law#Derivation_from_Planck's_law – G. Smith Oct 02 '19 at 04:22
  • @G.Smith I see, my bad, thanks for clarifying. – Jack Ceroni Oct 02 '19 at 12:52

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These are maxima of two different functions. The former, $\lambda_\text{max}$, is the maximum of the blackbody radiance per unit wavelength,

$$B_\lambda(\lambda,T)=\frac{2hc^2}{\lambda^5}\frac{1}{e^{hc/\lambda k_BT}-1}.$$

The latter, $\nu_\text{max}$, is the maximum of the blackbody radiance per unit frequency,

$$B_\nu(\nu,T)=\frac{2h\nu^3}{c^2}\frac{1}{e^{h\nu/k_BT}-1}.$$

Note that $B_\lambda$ and $B_\nu$ are not related by $\lambda\nu=c$; there is a fifth power of the wavelength but a third power of the frequency. Instead, they are related by

$$B_\lambda d\lambda=-B_\nu d\nu,$$

which expresses the fact that the radiance in a particular spectral interval is the same regardless of whether one is characterizing the spectrum by wavelength or by frequency.

Because they are two different functions, their maxima are not related by $\lambda\nu=c$.

G. Smith
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