The Wikipedia article Two-body problem in General Relativity uses two length-scale variables, $a$ and $b$, to simplify the math. For some information about these, consider these statements from the article:
They are constants of the motion and depend on the initial conditions (position and velocity) of the test particle.
and
Here, b can be interpreted as the distance of closest approach.
They first occur in this equation:
$$ \left( \frac{dr}{d\varphi} \right)^{2} = \frac{r^{4}}{b^{2}} - \left( 1 - \frac{r_{s}}{r} \right) \left( \frac{r^{4}}{a^{2}} + r^{2} \right) $$
Some of the prerequisite math can be found in other articles, and particularly Schwarzschild geodesics, where in the orbits of test particles section they give two equations that ostensibly define $a$ and $b$.
$$ \left( 1 - \frac{r_{s}}{r} \right) \left( \frac{dt}{d\tau} \right) = \frac{a}{b} $$
$$ r^{2} \left( \frac{d\varphi}{d\tau} \right) = a c $$
My first problem is that I don't understand how these define $a$ and $b$. As a previous quote implied, they should be calculable given initial conditions of a test particle, not depend on dynamic derivatives like the above equations imply. Let's return to the Two-body article. It mentions the following in-text, implying the straightforward expression of $a = h/c$.
The effective potential V can be re-written in terms of the length a = h/c
While not defined in that article, other articles on the subject give a consistent definition of $h$. Here, $L$ is angular momentum and $\mu$ is the reduced mass. Since we're only dealing with a test particle with low mass compared to the black hole, the reduced mass is its mass.
$$ h = L/ \mu = L / m$$
If you don't want it, we don't even have to include the particle's mass. Let's denote angular momentum as $L = \vec{r} \times m \vec{v}$, so we can write the following. This also implies an interpretation that $a$ is the specific relative angular momentum in the geometrized unit system.
$$ h = \vec{r} \times \vec{v} $$
$$ a = (\vec{r} \times \vec{v}) / c $$
This is even more complicated than necessary, since most of the work on the Two-body page takes motion to be in a single plane, which would eliminate the vector notation. To complete this question, let me explain that I would just solve for $b$ from the known expression of $a$ using one of the equations I've posted, but I don't have enough information. I can see that it would be necessary to have an expression relating $d \phi$ and $d \tau$, so I've searched through the information of Schwarzschild geodesics for this, I can't find it, and I suspect that's because of the simplifications introduced to do math for a test particle.
In summary, we have an interpretation for $b$ and an explicit equation for $a$. What is an explicit equation for $b$?