By the Young Tableaux construction, a triplet of $SU(2)$ (diagramatically, two boxes side by side) is supposed to be a two indices symmetric tensor.
However, one of the most known and minimal extensions of the standard model is that of adding a complex colorless scalar triplet in the $(\mathbf{1},\mathbf{3},1)$ representation of the SM group:
$$ \mathbf{\Phi} \equiv \begin{pmatrix} \frac{\Phi^0}{\sqrt{2}} & \Phi^{++} \\ \Phi^0 & -\frac{\Phi^0}{\sqrt{2}} \end{pmatrix}, $$
which is not symmetric. Why?
A lot of times I have seen the triplet appearing as $\epsilon\mathbf{\Phi}$, where $\epsilon$ is the rank-2 antisymmetric tensor, and this matrix product is indeed symmetric, but I don't know exactly what is happening.