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\newcommand{\ket}[1]{{\textstyle\left|{#1}\right>}}
\newcommand{\sqrtfrac}[2]{{\color{lightblue}{\textstyle\sqrt{\frac{#1}{#2}}}}}
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$There is no way to combine $\ket{1,0}$ and $\ket{\frac12, \frac12}$ to get a pure $j=\frac12$ state. The only possible value for the $z$-axis projection $m$ is $0 + \frac12 = \frac12$, but the total angular momentum can take either of $\frac12$ or $\frac32$.
The orthonormal combinations are given by the Clebsch-Gordan coefficients, which are usually presented in horrible tables like

The way to read this horrible table is that, if you wanted to construct the composite state like $\ket{\frac32,\frac12}$ or $\ket{\frac12,\frac12}$, you would read down the columns of the second table:
\begin{align}
\ket{\frac32,\frac12} &=
\sqrtfrac13\ \ket{1,1}\ket{\frac12,{-\frac12}}
+ \sqrtfrac23\ \ket{1,0}\ket{\frac12,{+\frac12}}
\\
\ket{\frac12,\frac12} &=
\sqrtfrac23\ \ket{1,1}\ket{\frac12,{-\frac12}}
- \sqrtfrac13\ \ket{1,0}\ket{\frac12,{+\frac12}}
\end{align}
If your constituent particles are in a pure state $\ket{1,0}\ket{\frac12,\frac12}$, your composite system is in a superposition of $\ket{\frac12,\frac12}$ and $\ket{\frac32,\frac12}$. You should convince yourself that you can find its coefficients either by solving the system of equations above for $\ket{1,0}\ket{\frac12, \frac12}$, or by reading across the Clebsch-Gordan table.