Degrees measure angles, while radians actually measure distance (in some sense). This is because a radian is defined as
the angle subtended from the center of a circle which intercepts an arc equal in length to the radius of the circle
(Source)
as can be seen in this animation:

(Source)
This makes the radian particularly useful when talking about rotational motion. For example, saying that you moved a distance of 2 radians makes a lot more sense than saying you moved a distance of, let's say, 30°.
So if you encounter radians, there is most often a (hidden) circle. This is also why radians are most commonly used for descibing trigonometric functions. On the other hand, describing the angle between a light ray hitting a mirror and the surface would usually be given in degrees.
This answer may be a bit unsatisfactory since you could always convert radians into degrees and back and you would be right, but this is the best that I can explain it. I'll leave you some links for further reading:
Radians vs. Degrees - physicsthisweek
Degrees vs. Radians - mathwithbaddrawings