What does it mean "atomic orbitals begin to interact" in d? It is misleading. Each dot is one "interaction". The plot shown is an accumulation of interactions, what dot is first and what dot is last is a matter of probabilities as in all quantum mechanics frames. (For example, see this answer for the double slit single electron experiment, where the interactions are built one electron at a time.)
What is happening is that the electrons of one atom, as the distance diminishes, start being shared by both atoms. This means that the wavefunctions describing the individual atoms have been modified an a new wavefunction with the combined geometry of both atoms is in effect.This happens in a large manner in lattices in crystals , where some of the electrons in metals, the conduction band, are shared/bound by the whole lattice.
As you must know each atom in the periodic table has its own configuration of electrons, and different wave functions describe it, but the mathematics allow for similar wavefunctions, so there are groupings, as the noble particles. The wavefunctions of the noble gases are such that the sharing described above as a new wavefunction does not happen for the specific electron configuration of the group of noble gases,.