I may try to provide for a simple explanation if possible.
Electric field at a point can also be understood as the force vector per unit charge at that point.
That means if I have a test charge q at some point, the direction of force acting on q will be the same as that of electric field at that point.
Now coming to your question, you are referring to electric field lines, which are just a representation of how electric fields occur in a given scenario.
If you take a point charge Q and a test charge q, and bring q desirably closer to Q, the electric field at any point will always be in the direction of the force acting between them, which in turn is along the line joining the two charges.
If you take this charge q towards Q from any "angle" around it, the electric field will still be in the direction of the force, like before.
For a fixed distance r between the charges, if you take q around Q along the circle of radius r, the electric field direction will be along the radius(since the radius is on the line joining the two charges).
Since the electric fields at every point equidistant from a charge are equal in magnitude, and the intensity of electric field is characterized by the density of electric field lines around that point, we can say that equidistant points have equal density of electric field lines.
So coming back to our circle of radius r, since every point on the path of the circle is equidistant from the charge Q, the density of electric field lines across equal sections of the circumference of the circle are equal. Hence we can see that the electric field lines are evenly distributed throughout the circumference. Therefore the electric field is in a radial direction.
My explanation, if wrong, may need correction. Hope this helps.