Chapter 1, problem 6 in Smythe's Static and Dynamics Electricity (2nd ed) reads
Charges $+4q$, $-q$ are placed at the points $A$, $B$, and $C$ is the point of equilibrium. Prove that the line of force that passes through $C$ meets $AB$ at an angle of $60^{\circ}$ at $A$ and at right angles at $C$. Find the angle at $A$ between $AB$ and the line of force that leaves $B$ at right angles to $AB$.
(Write potential for small region about $C$ in polar coordinates with origin at $C$.)
By an equilibrium point is meant a point in the field where an equipotential surface crosses itself at least twice, so that $\mathbf{E}=-\nabla V=0$ there.
While trying to solve this problem, I found that the point $C$ where $\mathbf E=0$ (excluding points infinitely far away) to be collinear with $A$ and $B$ and the field line is approximately as shown below.
My hang up at the moment is this: how can you prove that the field line passing through $C$ will pass this point perpendicular to the central line?
Intuitively, we might expect that lines of force (in isotropic homogeneous media) cross an axis of symmetry of a system of point charges at oblique angles if and only if there is a point charge on the axis at that location. Then, because the field line passes through an axis of symmetry, and no point charges are present, it must be perpendicular to the central line (neglect the case of a parallel line).
However, throughout the first chapter, Gauss's law in integral form is used to solve problems with field lines, and I'm hoping to find a more rigorous proof along these lines.