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Let's say I have an ideal gas of particles and the strike zone of area $\sigma=\pi d^2$ of a molecule of the molecule is what is the sub system considered. The end of the face of the cylinder is the strike zone. One may visualize it via 2 methods:

The continuum method:

enter image description here

Or the discrete method:

enter image description here

1. Continuum Mechanics

Resorting to continuum mechanics, then the fluid element (of a molecule) which will strike the target once every $\tau_F$ (the mean free time) on average. The magnitude of the force applied will be $P|\sigma|$. Intuitively, this makes sense as then the gas will have an internal pressure of $P$ (with each collision) and one will have a force frequency of $\bar F_{\nu}$

$$ \bar F_{\nu} = \frac{P |\sigma|}{\tau_F} $$

Note: $$\lim_{\tau_F \to 0}\bar F_{\nu} \tau_F = P |\sigma|$$ Does indeed give the correct equation $$|F| = P|\sigma|$$

Where $P$ is pressure and $\sigma$ is the area of a molecule.

2. Discrete Mechanics

Now, if I remain in the discrete case I have the gas exerting a force $F_C$ (which is renormalizable) during the interval of the collision $\tau_C$ a collision interval. In this case the force frequency is $\bar F_{\nu}' $

$$\bar F_{\nu}' = \frac{\langle |F_C| \rangle}{\tau_C} $$

Since both models are describing the same system, I was wondering if there prove/disprove this conjecture:

$$ \frac{P |\sigma|}{\tau_F} \approx \frac{\langle |F_C| \rangle}{\tau_C}$$

  • What exactly is your $F_C$ here? Is it the force per molecule or the total force from the gas? – By Symmetry Feb 15 '23 at 10:15
  • Force experienced by the face of the molecule on the time average in the interval $\tau_c$ – More Anonymous Feb 15 '23 at 10:28
  • How exactly is the function $\bar{F}{\nu}$ written, since the limit problems come down to integral equations? $\nu-->0$ or $\tau{F}$ – The Tiler Feb 20 '23 at 12:44
  • So the force frequency is defined by (time averaged force)/(time interval of force applied) – More Anonymous Feb 20 '23 at 12:46
  • @MoreAnonymous The wording of this question is very confusing. (1) What do you mean by "face of the molecule"? Molecules do not have faces, they are not cuboids. (2) Is the system you are considering simply an ideal gas of molecules? (3) What is the "strike zone area $A$"? Is this referring to a small area on the surface of the container? – Arturo don Juan Feb 22 '23 at 01:43
  • @ArturodonJuan when one calculates the mean free time. (1)One usually assumes a spherical model for the molecule.(3) The strike zone is the face of cylinder as shown in the image (2) Yes it is an ideal gas – More Anonymous Feb 22 '23 at 02:01

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