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I solved for the bound state energies of a system using the Dirac equation, I was told that to compare my result to the energies obtained with the Schrodinger equation I need to do the non-relativistic limit of that result. It should be similar to this question but I didn't manage to do it. Here's the expression

$$ E^2 = \displaystyle\frac{n^2\pi^2\hbar^2c^2}{L^2} + m^2c^4 \; . $$

Qmechanic
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  • I didn't manage to do it. Please show what you tried. What trouble are you having when you take the square root and expand $E$ as a Taylor series? – Ghoster Aug 19 '23 at 20:39

1 Answers1

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The relativistic energy squared is a multiple of mc^2 always. So you have

$$ E^2= m^2 \ c^4 \ \left(1+\frac{h^2 n^2}{c^2 L^2 m^2} \right) $$

The relativistic correction to the rest mass term is small, so use the expansion of the square root

$$ E = m c^2 \ \left(1+ \frac{h^2 n^2}{2 c^2 L^2 m^2}\right) = m c^2 +\frac{1}{2m } \left( \frac{n h}{L}\right)^2 $$

$$ p =\frac{n h}{L}$$

has the dimension of momentum, so the nonrelativistic kinetic energy is as usual $p^2/(2m)$, where p is the absolute value of momentum of a standing wave in an intervall of length $L$ with n nodes.