It will never do a pure rotation about the COM as long as there is a force applied, because this force imparts an impulse which will accelerate the center of mass.
The geometry of the problem is as such

When a force is applied a distance $d$ from the center of mass, the body will have an instantaneous rotational acceleration (Eulerian acceleration) about a point at a distance $c$ from the other side of the center of mass. The distance is
$$ c = \frac{I_{\rm CM}}{m d} = \frac{ \kappa^2}{d} \tag{1} $$
where $\kappa$ is the radius of gyration of the body about the axis of rotation at the center of mass, and $I_{\rm CM}$ the mass moment of inertia at the center of mass.
The above relationship is purely geometrical and since the application point does not change, and the radius of gyration is assumed to be fixed, the resulting rotation point is also fixed relative to the center of mass and the orientation of the body.
Only when the distance $d$ approaches infinity, does the rotation center $c$ near the center of mass. On the other hand, if the force-distance nears zero, the rotation center goes to infinity and the body purely translates (in an accelerating fashion).
Edit The statement below is incorrect.
In deciphering the tracks of the CoM shown, place the pivot point at the center of the circles, and the CoM rotates about the pivot point at a radius $c$ as shown above.
I think what might be going on is when the tracks are near circular, the rod is actually tangent to the track and the force pointing inwards. The radius of orbit $r$ is not the same as the pivot distance $c$. The radius of orbit is such that the force is $F \approx m \omega^2 r$ (when near-circular orbits).
To derive (1) apply an impulse $F {\rm d}t$ at a distance $d$ from the center of mass. Use the equations of motion summed at the center of mass to get the response
$$ \begin{aligned}
F {\rm d}t & = m {\rm d}v \\
d\; F{\rm d}t & = I {\rm d}\omega
\end{aligned}$$
and note that if the body is pivoted about a point located $c$ distance from the center of mass, then the velocity at the CoM is $${\rm d}v = c \, {\rm d}\omega$$
If you divide the top expression from the bottom expression you have
$$ \frac{d \, F {\rm d}t}{F {\rm d}t} = \frac{ I {\rm d}\omega}{m c {\rm d}\omega} $$ which is solved for $$\boxed{c = \frac{I}{m \,d} = \frac{\kappa^2}{d} }$$ when $I = m \kappa^2$.