When quantizing a system, what is the more (physically) fundamental commutation relation, $[q,p]$ or $[a,a^\dagger]$? (or are they completely equivalent?)
For instance, in Peskin & Schroeder's QFT, section 3.5, when trying to quantize the Dirac field, they first say what commutation relation they expect to get for $[\Psi(\vec{x}),\Psi^\dagger(\vec{y})]$ (where $i\Psi^\dagger$ is the conjugate momentum to $\Psi$), in analogy to the Klein-Gordon field, then they postulate a commutation relation between $[a^r_{\vec{p}},a^{s\dagger}_{\vec{q}}]$ etc., and then verify that they indeed get what they expected for $[\Psi(\vec{x}),\Psi^\dagger(\vec{y})]$.
Why did we need to postulate the value of $[a^r_{\vec{p}},a^{s\dagger}_{\vec{q}}]$? Couldn't we have just computed it off of $[\Psi(\vec{x}),\Psi^\dagger(\vec{y})]$? (which, by expecting to get it, we could have just as well already postulated it).
I suppose that would entail explicitly writing something like: $$ a_{\vec{p}}^r = \frac{1}{\sqrt{2E_{\vec{p}}}} u^{r\dagger}(\vec{p})\int_{\mathbb{R}^3}d^3\vec{x}\,e^{-i\vec{p}\cdot\vec{x}}\Psi(\vec{x})$$ and a similar expression for $b$.