As a lowly physics undergrad who has been chewing on this 2nd postulate of special relativity for a year or more, I simply can't wrap my head around reasons why it is true or how Einstein might have been convinced enough to propose this postulate.
Consider Alfred who is riding in a car travelling at 88 m/s with his headlights on and Bernard who is on the side of the road hitch hiking. Why does the light propagating from Alfred's car move at $c$ relative to both Alfred and Bernard, and not at $c$ + 88 m/s relative to Bernard?
The nifty results of special relativity all kind of hinge on this idea, and asking my professors in class hasnt really yielded an answer much more than "because we have never observed a case otherwise".