Superposition does not "exist," as much as it is a mathematical tool that we use to describe the world that does exist. We can't measure it because its not something to be measured.
Superposition is a concept in mathematics. A function has the property of superposition iff:
$$f(x_1+x_2) = f(x_1) + f(x_2)$$
$$f(ax) = af(x)$$
Any system which satisfies this property is said to have superposition. That's all.
The quantum physics principle you are referring to is that the quantum states of the system have superposition. This lets me say things like "The spin of the electron is a superposition of spin up and spin down." What experiments like the double-slit experiment show is that intuitive explanations which assume the spin is either up or down fail to properly predict what we show experimentally. We see experimental evidence that suggests that theories which assume the spin is either up or down yield incorrect results, as does the assumption that its spin is the "average" of spin up and spin down. We then show that the behavior is well predicted by the quantum mechanics, and that behavior has the property of superposition.
You can actually "solve" quantum mechanics waveforms without using the principle of superposition. You don't have to use that property at all. However, it becomes intractable very quickly. The fact that the equations of quantum mechanics permit us to treat a state as a superposition of several states simplifies the mathematics for us dramatically.