Note: this is NOT a question why current is the base unit as opposed to charge—that’s because measuring $1 \ \mathrm{ A }$ through a wire is easier to measure in a lab than is $1 \ \mathrm{ C }$ in free space; the question explores why electric units are chosen as base units in the SI in the first place. I am familiar with this question and have referred to it before. It does not answer my question.
Of course, according to Coulomb’s law, given equal base charges $q$, $F \propto \left. q^2 \middle/ r^2 \right.$.
For hypothetical purposes, consider a new unit of electrical charge—call it a $\mathrm{ \Xi }$ for fun.
Thus,
$$\begin{align} 1 \ \mathrm{ N } = 1 \ \left.\mathrm{ \mathrm{ kg }\!\cdot\!\mathrm{ m } }\middle/\mathrm{ s }^2\right. &\propto 1 \ \left.\mathrm{ \Xi }^2\middle/\mathrm{ m }^2\right. \\ 1 \ \left.\mathrm{ \mathrm{ kg }\!\cdot\!\mathrm{ m }^3 }\middle/\mathrm{ s }^2\right. &\propto 1 \ \mathrm{ \Xi }^2 \\ 1 \ \mathrm{ kg }^{ \left. 1 \middle/ 2 \right. }\!\cdot\!\mathrm{ m }^{ \left. 3 \middle/ 2 \right. }\!\cdot\!\mathrm{s}^{ -1 } &\propto 1 \ \mathrm{ \Xi }\\ \end{align}$$
It’s at this point that you can probably see why electrical units seem a bit less fundamental to me. Although the exponents aren’t integral numbers, a unit of electrical charge has still been expressed in terms of mass, length, and time, arguably the most fundamental units in our world.
In fact, as I understand, this is the dimensional form that the Gaussian unit statcoulomb aka franklin aka electrostatic unit of charge takes.
So why is an electrical unit in the base units of the SI if they can be defined in terms of mass, length and time? Why not define a unit of current that takes the form $\mathrm{ kg }^{ \left. 1 \middle/ 2 \right. }\!\cdot\!\mathrm{ m }^{ \left. 3 \middle/ 2 \right. }\!\cdot\!\mathrm{s}^{ -2 }\ $ instead of $\mathrm{A}$?
Also, in response to @Spirine’s answer, do systems of natural units (e.g., $\left.\mathrm{ MeV }\middle/ c^2 \right.$ from base $\mathrm{ eV }$) essentially have only one fundamental unit?