Consider a disk with a radius $R$ (I'll use $R=1$ at various points here) that has a constant surface charge density $\sigma$. Unlike the similar problem of the field in the vicinity of a infinitely thin ring, the field directly above the disk is very well behaved. Like the case of an infinite sheet of constant surface charge, the field limits to a constant as you get closer to the surface, and a point on the surface has a defined electrical potential.
This recent paper gives equations for the specific case of points on the plane of the disk. Since we have rotational symmetry, there is only one variable, $\rho$, the distance from the axis of rotational symmetry. Graph from the paper:
As you can imagine, the point of the highest slope is the edge of the disk. Is the slope (field) at this point infinite? From what I can make out of their equations, signs seem to point to "yes". The Elliptic functions are tricky, however, and I don't trust my conclusions. Up to the point $\rho=R$, the form of the above function is:
$$ V(\rho) = V(0) \frac{2}{\pi} E(\rho)$$
Here, $E(\rho)$ is an elliptic function, and is different from the paper, because it uses the "Matlab" convention while I use the "Wikipedia" convention. The slope of E() doesn't look convincingly upright, but the derivative seems to indicate it should be. I'm also troubled by the fact that I can't seem to numerically observe a divergence at $\rho=0.9999999999$.
The physics at play are even more perplexing to me. I expected that a 2D surface, any 2D surface, would have a finite field on its face. Not so for a line, I understand that. But the ring that defines the edge of the disk only has a differential amount of charge on it.
Consider another thought experiment: start at $\rho=1$ and $z=0$, I'll denote it $(1,0)$. Now move upward, but keep $\rho$ the same. If you're at $(1,0.001)$ you should have a finite field. But what happens as $z\rightarrow 0$? Does it just jump from a defined finite value to infinity? What on Earth is going on with the electric field in the vicinity of this edge, or ANY edge of a 2D surface for that matter?