This is the conjugate representation of SU(2). It is the backbone of the fermion masses in the SM and is detailed in standard SM texts.
That is to say, for the doublet,
$$
\tilde H \equiv i\sigma_2 H^*,
$$
so it transforms identically to H under SU(2)! (It, of course, reverses the hypercharge).
Behold:
$$
\delta H = \frac{i}{2} \theta_a \sigma_a H \qquad \leadsto \\
\delta \tilde H = i\sigma_2 ( \frac{i}{2} \theta_a \sigma_a H )^* \qquad \\
= i\sigma_2 ( -\frac{i}{2} \theta_a \sigma_a^* H^* ) = \frac{i}{2} \theta_a \sigma_a ~ i\sigma_2 H ^* = \frac{i}{2} \theta_a \sigma_a \tilde H ,
$$
by virtue of $\sigma_2 \sigma_a^*+\sigma_a\sigma_2=0 $ for any a!
So, $\tilde H$ is a doublet just like H, except stood on its head, complex conjugated, with an extra - sign at the bottom.
As a result, the Yukawa coupling you exemplify, which is identical to the Yukawa of the SM for the standard Higgs doublet , provides masses for both the uplike quarks, the first term, and the downlike quarks.
That is so because
$$
\langle H\rangle_0= \begin{pmatrix} 0\\ v \end{pmatrix} , \qquad \implies \qquad \langle \tilde H\rangle_0=\begin{pmatrix} v\\ 0 \end{pmatrix} ,
$$
so the v.e.v. of $\tilde H$ provides the uplike quark masses, just like that of the H for the downlike masses.
As for the Higgs triplet, I am not very experienced with its standard conventions. You dot your triplet (which is in the spherical basis) properly transformed to a Cartesian vector, now, to the Pauli vector, and re-express it in the spherical basis again to monitor the properties of the individual components,
$$
\Delta=\begin{pmatrix} {\chi^{+}} &{\sqrt{2}} \chi^{++} \\
{\sqrt{2}}\chi ^0 & - \chi^{+} \end{pmatrix}= \chi^+ \sigma_3 +\chi^{++} \frac{\sigma_1+i\sigma_2}{\sqrt{2}} + \chi^0 \frac{\sigma_1-i\sigma_2}{\sqrt{2}} ,
$$
and read off the new (transformed) components in the adjoint object $$i\sigma_2 \Delta^* (-i\sigma_2) ,$$ noting the transposition effected. (Full disclosure: I seem to be getting a couple of errant - signs extra, contrasted to your expression. It may well be an artifact of the procedure. The v.e.v. is very much in the properly transposed position, as you should check!)