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For the free particle in 3d, I follow Robinett's page 491 to find that the solutions to the radial equation are the spherical Bessel function $j_l(z)$ and $y_l(z)$ where $z=kr$ and $k=\sqrt{\frac{2mE}{\hbar^2}}$.

If I allow for a constant potential $V=V_0$, and consider the $E<V$ case, then since the state are bound, I only use the regular Bessels $j_l(z)$.

I am struggling to figure out the other things that change in the solution. Wikipedia state the following:

$$ R(r) = A j_l (z) $$ with

$$ z= \sqrt{\frac{2m(E-V_0)}{\hbar^2}} r $$ and $A$ is some normalization.

  1. Why is it $E$ MINUS $V_0$? if $E<V$ then this is negative and the function is imaginary from the $\sqrt{-1}$ no? Wiki is unclear on this, since they state

"We first consider bound states, i.e., states which display the particle mostly inside the box (confined states). Those have an energy E less than the potential outside the sphere, i.e., they have negative energy..."

but then directly below the $R(r)$ solution there is a contradiction with this:

"Note that for bound states, $ V_{0}<E<0$"

  1. How is the normalization constant A solved for from the boundary conditions?
Lopey Tall
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  • I think you should have a look at this: https://quantummechanics.ucsd.edu/ph130a/130_notes/node227.html – Gert Nov 11 '20 at 21:01
  • @gert thank you for the reference! huh. it looks like I should be more concerned with the Hankel functions, since I an interested in the E < V case. Hmm more to think about. thank you – Lopey Tall Nov 11 '20 at 21:13
  • You're welcome. – Gert Nov 11 '20 at 21:14
  • @gert i think the issue with using this constructure is that I would be assuming a barrier at some values of r. What if I am considering a constant potential everywhere? simply considering a state with E less than that V – Lopey Tall Nov 11 '20 at 21:32
  • It's not really a barrier, rather a boundary. W/o boundaries there can be no bound states (eigenstates). If $V=V_0$ EVERYWHERE you don't need to use spherical coordinates, you can use Cartesian $(x,y,z)$ coordinates. It's quite pointless IMO... – Gert Nov 11 '20 at 21:41

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