Questions tagged [schroedinger-equation]

Partial differential equation which describes the time evolution of the wavefunction of a quantum system. It is one of the first and most fundamental equations of quantum mechanics.

When to use this tag

Use the tag if you have a question specifically relating to the Schrödinger equation, such as its derivation or the particular form of the Schrödinger equation for a given problem. In general, you will also want to tag your question as .

Introduction

The general, time-dependent Schrödinger equation is

$$ i \hbar \frac{\partial}{\partial t} \Psi(x,t) = \hat H \Psi $$

with the Hamiltonian $\hat H$ and the wave function $\Psi(x,t)$. For a single, non-relativist particle, this is equal to

$$ i \hbar \frac{\partial}{\partial t} \Psi(x,t) = \left( \frac{-\hbar^2}{2m} \nabla^2 + V(x,t) \right) \Psi(x,t) \quad .$$

If the potential $V(x,t)$ is not time-dependent, this equation separates and gives the time-independent Schrödinger equation, which is just the eigenvalue equation for the Hamilton operator:

$$ \hat H \Psi(x,t) = E \Psi(x,t) $$

The Schrödinger equation describes the time evolution of states/wave functions in the Schrödinger picture. If one instead chooses to work in the Heisenberg picture, where states are time-independent and instead operators change in time, the governing equation is

$$ \frac{\mathrm{d}}{\mathrm{d}t} \hat A(t) = \frac{i}{\hbar} [ \hat H , \hat A(t) ] + \frac{\partial}{\partial t} A(t) \quad.$$

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Why can't the Schrödinger equation be derived?

Honestly, I don't get it. People say it's because it's a postulate. But, I mean, I see people deriving the Schrödinger equation with the help of the wave function, $T+U$ and partial differentials in three space coordinates and one time coordinate.…
anon
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2 answers

Is the potential energy term of the Schrodinger equation correct?

The nonhomogeneous heat equation is of the form: $$\frac{\partial }{\partial t} u(x,t) = \alpha^2 \frac{\partial^2}{\partial x^2} u(x,t) + f(x,t)$$ it appears as though we can always find some $g(x,t)$ and have written it with the substitution…
user92640
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Analytic solutions to time-dependent Schrödinger equation

Are there analytic solutions to the time-Dependent Schrödinger equation, or is the equation too non-linear to solve non-numerically? Specifically - are there solutions to time-Dependent Schrödinger wave function for an Infinite Potential Step, both…
metzgeer
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Why are there so many Schrödinger equations?

Why are there so many Schrödinger equations? I have been looking through many pages about the Schrödinger equation, yet every page I seem to find has a different variation of it. Many are similar, But I don't know what to trust. Are they all just…
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Schrödinger equation with spatially dependent mass

I am solving the Schrödinger equation for a particle in a hybrid system. Specifically I have to solve the following differential equation $$ - \frac{\hbar^2}{2}\frac{d}{dx}\left(\frac{1}{m^{*}(x)}\frac{d\psi}{dx}\right) -\frac{\hbar^2}{2m^{*}(x)}…
user13514
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What is the relationship between spherical harmonics and the schrodinger equation?

Spherical harmonics (below image) Schrodinger equation (below image) What is the relationship between spherical harmonics and the schrodinger equation?
Dale
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Schrödinger's equation relation to quantum numbers

I tried searching for an answer everywhere but the equation is either solved from the physical point of view or they just cite it in chemistry textbooks without even showing how it is made to talk about orbitals. What I was curious about, is how,…
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Solving Schrödinger's equation for atoms without forcing antisymmetry

Time independent Schrödinger's equation neglects spin. What is expected to get by solving that equation for atoms without forcing antisymmetry of wave function with the permutation of coordinates of electrons? There are methods that impose…
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How can we derive the schrodinger wave equation?

How can we derive the Schrodinger wave equation with simplified explanation?
sanjeeb
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How much the probability wave acts like a wave?

A superposition of two probability wave creates standing wave. Well, that is convincing. Dose waves described by schrodinger's equation have other properties of wave? like reflection, refraction, polarization ect.
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Why do sinusoids appear in the Schrodinger equation?

Pretty much what it says in the title. For example, in the ‘particle in an infinite square potential well’ problem, we represent the wave function using sinusoids. As these are zero valued at the bounds. However, could we also choose a different…
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Potential step solution is not normalizable

If you try to integrate the solution of the potential step, http://en.wikipedia.org/wiki/Solution_of_Schr%C3%B6dinger_equation_for_a_step_potential#Solution you will notice that it diverges! Doesn't that mean that the solution is physically…
Rafid
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3d particle in a constant potential radial equation

For the free particle in 3d, I follow Robinett's page 491 to find that the solutions to the radial equation are the spherical Bessel function $j_l(z)$ and $y_l(z)$ where $z=kr$ and $k=\sqrt{\frac{2mE}{\hbar^2}}$. If I allow for a constant potential…
Lopey Tall
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What is this equation used for? $\gamma^\mu(i\partial_\mu-eA_\mu)\psi=m\psi$

As perhaps a mathematical scavenger hunt, my mother (knowing my interest in physics and math equations), sent me this image out of curiosity for what it was. Here is the same equation taken from the…
Graviton
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Is there an analog of the Kirchhoff integral theorem applied to the Schrodinger equation?

The Kirchhoff integral formula is a powerful tool that allows us to compute solutions to the standard wave equation given certain 2D boundary conditions. Is there anything similar that holds for the Schrodinger equation? I suspect the answer is no,…
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